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- W2166009960 endingPage "933" @default.
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- W2166009960 abstract "This study was aimed at integrating a green separation process without phase change, namely nanofiltration, with olefin metathesis to recover the homogeneous catalyst. As the commercially available Hoveyda II catalyst was not sufficiently retained by the membrane, a set of homogeneous ruthenium-based catalysts were prepared to enhance the recovery of the catalyst by solvent-resistant commercial membranes made of polyimide (Starmem 228). The molecular weights of the catalysts were gradually increased from 627 to 2195 g mol−1, and recovery was found to increase from around 70 % to 90 % both in toluene and dimethyl carbonate. The most retained catalyst was then engaged in a series of model ring-closing metathesis reactions associated to a final nanofiltration step to recover and recycle the catalyst. Up to five cycles could be performed before a deterioration in the performance of the process was observed." @default.
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- W2166009960 date "2008-11-24" @default.
- W2166009960 modified "2023-09-28" @default.
- W2166009960 title "Recovery of Enlarged Olefin Metathesis Catalysts by Nanofiltration in an Eco-Friendly Solvent" @default.
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- W2166009960 doi "https://doi.org/10.1002/cssc.200800152" @default.
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