FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2166012955> ?p ?o ?g. }

• W2166012955 endingPage "282" @default.
• W2166012955 startingPage "271" @default.
• W2166012955 abstract "The complexes [RuIII(EDTA—H)NO]BF4 1 and [RuIII(EDTA)(NO)] 1a were synthesized and characterised by elemental analysis, IR and UV—Vis spectroscopy, conductivity, magnetic susceptibility, EPR and electrochemical studies. Complex 1a catalyses the oxidation by molecular oxygen of 1-hexene to 2-hexanone and cyclohexene to cyclohexene oxide through the ligand-mediated RuIII—EDTA—NO 1a/Ruv—EDTA—NO2 2 oxygen atom transfer. The oxidation reactions were studied in 7:3 ethanol—water medium in the temperature range 30–45 °C (μ=0.1 M KCl). The oxidation of 1-hexene and cyclohexene proceeds with a turnover number of 50 and 44 moles product per mole catalyst per hour. The rate of oxidation is first order with respect to catalyst concentration and one-half order with respect to molecular oxygen concentration. At higher substrate concentrations, the reaction rate was found to be independent of substrate concentration. 18O2 studies indicate that the source of O atom transferred to the substrate is from molecular O2. The formation of an organometallic metallocyclic intermediate is proposed for the reaction. The rate of oxygenation of cyclohexene by iodosyl benzene catalyzed by 1a was found to be identical with that obtained with O2 as oxidant. The rate of oxygenation of 1a to 2 was studied independently by an O atom transfer from iodosyl benzene." @default.
• W2166012955 created "2016-06-24" @default.
• W2166012955 creator A5002948333 @default.
• W2166012955 creator A5005962226 @default.
• W2166012955 creator A5011127281 @default.
• W2166012955 creator A5012100549 @default.
• W2166012955 creator A5029553164 @default.
• W2166012955 creator A5056012165 @default.
• W2166012955 creator A5067078331 @default.
• W2166012955 date "1992-03-01" @default.
• W2166012955 modified "2023-09-24" @default.
• W2166012955 title "Nitrosyl ethylenediaminetetraacetato ruthemium(III) — an efficient oxygen atom transfer agent for the oxidation of olefins by molecular O2 and PhIO through ligand-mediated nitrosyl/nitro couple" @default.
• W2166012955 cites W1964290456 @default.
• W2166012955 cites W1964357532 @default.
• W2166012955 cites W1972021288 @default.
• W2166012955 cites W1978365821 @default.
• W2166012955 cites W1981157583 @default.
• W2166012955 cites W1987865771 @default.
• W2166012955 cites W1989254458 @default.
• W2166012955 cites W2010815782 @default.
• W2166012955 cites W2016044737 @default.
• W2166012955 cites W2044689826 @default.
• W2166012955 cites W2055013092 @default.
• W2166012955 cites W2056874984 @default.
• W2166012955 cites W2084307691 @default.
• W2166012955 cites W2093698530 @default.
• W2166012955 cites W2095463630 @default.
• W2166012955 cites W2099037802 @default.
• W2166012955 cites W2952392906 @default.
• W2166012955 cites W3005517822 @default.
• W2166012955 cites W3137440310 @default.
• W2166012955 cites W4239548194 @default.
• W2166012955 cites W4254084766 @default.
• W2166012955 cites W2345497887 @default.
• W2166012955 doi "https://doi.org/10.1016/0304-5102(92)85005-z" @default.
• W2166012955 hasPublicationYear "1992" @default.
• W2166012955 type Work @default.
• W2166012955 sameAs 2166012955 @default.
• W2166012955 citedByCount "12" @default.
• W2166012955 countsByYear W21660129552017 @default.
• W2166012955 countsByYear W21660129552021 @default.
• W2166012955 crossrefType "journal-article" @default.
• W2166012955 hasAuthorship W2166012955A5002948333 @default.
• W2166012955 hasAuthorship W2166012955A5005962226 @default.
• W2166012955 hasAuthorship W2166012955A5011127281 @default.
• W2166012955 hasAuthorship W2166012955A5012100549 @default.
• W2166012955 hasAuthorship W2166012955A5029553164 @default.
• W2166012955 hasAuthorship W2166012955A5056012165 @default.
• W2166012955 hasAuthorship W2166012955A5067078331 @default.
• W2166012955 hasConcept C116569031 @default.
• W2166012955 hasConcept C149635348 @default.
• W2166012955 hasConcept C161790260 @default.
• W2166012955 hasConcept C170493617 @default.
• W2166012955 hasConcept C178790620 @default.
• W2166012955 hasConcept C185592680 @default.
• W2166012955 hasConcept C21951064 @default.
• W2166012955 hasConcept C2780263894 @default.
• W2166012955 hasConcept C2780639532 @default.
• W2166012955 hasConcept C2992086430 @default.
• W2166012955 hasConcept C2994492776 @default.
• W2166012955 hasConcept C32909587 @default.
• W2166012955 hasConcept C41008148 @default.
• W2166012955 hasConcept C540031477 @default.
• W2166012955 hasConcept C55493867 @default.
• W2166012955 hasConcept C58312451 @default.
• W2166012955 hasConcept C75473681 @default.
• W2166012955 hasConceptScore W2166012955C116569031 @default.
• W2166012955 hasConceptScore W2166012955C149635348 @default.
• W2166012955 hasConceptScore W2166012955C161790260 @default.
• W2166012955 hasConceptScore W2166012955C170493617 @default.
• W2166012955 hasConceptScore W2166012955C178790620 @default.
• W2166012955 hasConceptScore W2166012955C185592680 @default.
• W2166012955 hasConceptScore W2166012955C21951064 @default.
• W2166012955 hasConceptScore W2166012955C2780263894 @default.
• W2166012955 hasConceptScore W2166012955C2780639532 @default.
• W2166012955 hasConceptScore W2166012955C2992086430 @default.
• W2166012955 hasConceptScore W2166012955C2994492776 @default.
• W2166012955 hasConceptScore W2166012955C32909587 @default.
• W2166012955 hasConceptScore W2166012955C41008148 @default.
• W2166012955 hasConceptScore W2166012955C540031477 @default.
• W2166012955 hasConceptScore W2166012955C55493867 @default.
• W2166012955 hasConceptScore W2166012955C58312451 @default.
• W2166012955 hasConceptScore W2166012955C75473681 @default.
• W2166012955 hasIssue "3" @default.
• W2166012955 hasLocation W21660129551 @default.
• W2166012955 hasOpenAccess W2166012955 @default.
• W2166012955 hasPrimaryLocation W21660129551 @default.
• W2166012955 hasRelatedWork W1971101722 @default.
• W2166012955 hasRelatedWork W2003493240 @default.
• W2166012955 hasRelatedWork W2023391699 @default.
• W2166012955 hasRelatedWork W2041467227 @default.
• W2166012955 hasRelatedWork W2080217121 @default.
• W2166012955 hasRelatedWork W2081434063 @default.
• W2166012955 hasRelatedWork W2179047114 @default.
• W2166012955 hasRelatedWork W2333417161 @default.
• W2166012955 hasRelatedWork W2352284304 @default.
• W2166012955 hasRelatedWork W2395154391 @default.
• W2166012955 hasVolume "72" @default.

• next