Matches in SemOpenAlex for { <https://semopenalex.org/work/W2166023818> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W2166023818 endingPage "2327" @default.
- W2166023818 startingPage "2321" @default.
- W2166023818 abstract "In the ion-transfer kinetic model at the immiscible liquid/liquid interface presented here, the transfer of an ion is controlled by an activation energy and velocity of the ion in the viscous interface. The model was enlightened by the insufficient agreement of the potential dependence of the experimental transfer coefficient with the Butler equation and by a loss of a reasonable physical meaning in the activationless kinetic theory based on the Nernst-Planck equation. The velocity of the large spherical ion in this model was driven by the desolvation energy, the energy of overcoming the interfacial tension between the two liquids, the electrostatic energy in the double layer, and the thermal fluctuation. It is retarded by the viscous force, as expressed by the Langevin equation. The activation energy resulted from the first three energies. The kinetic equation was derived from the expressions for the velocity and the activation energy through the Boltzmann's distribution equation. It could elucidate both properties of the activation control and of the viscous control. The equilibrium condition did not lead to the Nernst equation because the frictional energy should be compensated with the potential difference between the two phases. The logarithmic forward rate constant was approximately linear with the potential difference. However, the theory could not explain quantitatively the non-linearity observed experimentally for small non-spherical anions." @default.
- W2166023818 created "2016-06-24" @default.
- W2166023818 creator A5039028021 @default.
- W2166023818 date "1996-07-01" @default.
- W2166023818 modified "2023-09-30" @default.
- W2166023818 title "Theory of ion-transfer kinetics at a viscous immiscible liquid/liquid interface by means of the langevin equation" @default.
- W2166023818 cites W1533259530 @default.
- W2166023818 cites W1586999554 @default.
- W2166023818 cites W1593358117 @default.
- W2166023818 cites W1601401141 @default.
- W2166023818 cites W1973630034 @default.
- W2166023818 cites W1975376223 @default.
- W2166023818 cites W1979384152 @default.
- W2166023818 cites W1982770801 @default.
- W2166023818 cites W1984013971 @default.
- W2166023818 cites W1985305864 @default.
- W2166023818 cites W2014452230 @default.
- W2166023818 cites W2024292356 @default.
- W2166023818 cites W2030470000 @default.
- W2166023818 cites W2039720747 @default.
- W2166023818 cites W2048736621 @default.
- W2166023818 cites W2052022435 @default.
- W2166023818 cites W2068229027 @default.
- W2166023818 cites W2082382141 @default.
- W2166023818 cites W2090489627 @default.
- W2166023818 cites W2090957479 @default.
- W2166023818 cites W2092700904 @default.
- W2166023818 cites W2147142035 @default.
- W2166023818 cites W2174711518 @default.
- W2166023818 cites W2505782076 @default.
- W2166023818 cites W4234211333 @default.
- W2166023818 doi "https://doi.org/10.1016/0013-4686(96)00062-x" @default.
- W2166023818 hasPublicationYear "1996" @default.
- W2166023818 type Work @default.
- W2166023818 sameAs 2166023818 @default.
- W2166023818 citedByCount "20" @default.
- W2166023818 countsByYear W21660238182012 @default.
- W2166023818 countsByYear W21660238182015 @default.
- W2166023818 countsByYear W21660238182016 @default.
- W2166023818 countsByYear W21660238182021 @default.
- W2166023818 countsByYear W21660238182022 @default.
- W2166023818 crossrefType "journal-article" @default.
- W2166023818 hasAuthorship W2166023818A5039028021 @default.
- W2166023818 hasConcept C121332964 @default.
- W2166023818 hasConcept C135889238 @default.
- W2166023818 hasConcept C145148216 @default.
- W2166023818 hasConcept C147789679 @default.
- W2166023818 hasConcept C17525397 @default.
- W2166023818 hasConcept C178790620 @default.
- W2166023818 hasConcept C184501600 @default.
- W2166023818 hasConcept C185592680 @default.
- W2166023818 hasConcept C2777577648 @default.
- W2166023818 hasConcept C5637370 @default.
- W2166023818 hasConcept C74650414 @default.
- W2166023818 hasConcept C8892853 @default.
- W2166023818 hasConcept C97355855 @default.
- W2166023818 hasConceptScore W2166023818C121332964 @default.
- W2166023818 hasConceptScore W2166023818C135889238 @default.
- W2166023818 hasConceptScore W2166023818C145148216 @default.
- W2166023818 hasConceptScore W2166023818C147789679 @default.
- W2166023818 hasConceptScore W2166023818C17525397 @default.
- W2166023818 hasConceptScore W2166023818C178790620 @default.
- W2166023818 hasConceptScore W2166023818C184501600 @default.
- W2166023818 hasConceptScore W2166023818C185592680 @default.
- W2166023818 hasConceptScore W2166023818C2777577648 @default.
- W2166023818 hasConceptScore W2166023818C5637370 @default.
- W2166023818 hasConceptScore W2166023818C74650414 @default.
- W2166023818 hasConceptScore W2166023818C8892853 @default.
- W2166023818 hasConceptScore W2166023818C97355855 @default.
- W2166023818 hasIssue "14" @default.
- W2166023818 hasLocation W21660238181 @default.
- W2166023818 hasOpenAccess W2166023818 @default.
- W2166023818 hasPrimaryLocation W21660238181 @default.
- W2166023818 hasRelatedWork W1972553463 @default.
- W2166023818 hasRelatedWork W1974182091 @default.
- W2166023818 hasRelatedWork W2002044310 @default.
- W2166023818 hasRelatedWork W2063194445 @default.
- W2166023818 hasRelatedWork W2082968979 @default.
- W2166023818 hasRelatedWork W2083083864 @default.
- W2166023818 hasRelatedWork W2166023818 @default.
- W2166023818 hasRelatedWork W2313435329 @default.
- W2166023818 hasRelatedWork W2521193346 @default.
- W2166023818 hasRelatedWork W2309391741 @default.
- W2166023818 hasVolume "41" @default.
- W2166023818 isParatext "false" @default.
- W2166023818 isRetracted "false" @default.
- W2166023818 magId "2166023818" @default.
- W2166023818 workType "article" @default.