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- W2166027412 abstract "A simple route to the highly substituted enantiomerically pure 1,3-alkadienes 3 is provided by the rearrangement of the adduct prepared from the allene 1 (CbC(O)NiPr2, R′ =; (C6H5CH2)) and the ketene N,O-acetal 2 (RCH3). The transition state for the rearrangement could be determined from knowledge of the absolute configurations of the educt 1 and the product 3." @default.
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- W2166027412 date "1985-08-01" @default.
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- W2166027412 title "Allene Claisen Rearrangement with 1,4-Chirality Transfer" @default.
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- W2166027412 doi "https://doi.org/10.1002/anie.198507001" @default.
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