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- W2166054741 abstract "Abstract Carbohydrate‐modified carbene complexes can be synthesised by combining a sugar electrophile with a metalate nucleophile or vice versa. Acyclic sugar skeletons adopt conformations that are controlled by the minimisation of 1,3‐interactions and are not significantly affected by the incorporation of a metal fragment. Thus, the latter can be used exclusively for reactivity tuning. Sugar carbene complexes undergo regio‐ and stereoselective ligand‐ and metal‐centred reactions such as C 2 ‐homologisation and benzannulation." @default.
- W2166054741 created "2016-06-24" @default.
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- W2166054741 date "1997-11-01" @default.
- W2166054741 modified "2023-10-09" @default.
- W2166054741 title "Carbohydrate‐Modified Metal Carbenes: Synthesis And First Applications" @default.
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- W2166054741 doi "https://doi.org/10.1002/chem.19970031105" @default.
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