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- W2166066714 abstract "This work summarizes the results of our studies on the spectral, magnetic, electrochemical and chemical redox properties of N-cycloalkyl-3,5-(t)Bu(2)-salicylaldimine ligands [cycloalkyl=cyclo-C(5)H(9)(HL(1)), cyclo-C(6)H(11) (HL(2)), cyclo-C(7)H(13) (HL(3)), cyclo-C(8)H(15) (HL(4)), 1-adamantyl (HL(5)), 2-adamantyl (HL(6))] and their copper(II) complexes (1-6). The compounds have been characterized by IR, (1)H NMR, UV-vis, EPR spectroscopy, electrochemical and magnetic susceptibility measurements. The geometry of 1-6, according to their EPR (g(II) and g(II)/A(II)) and visible spectral data, exhibit a significant amount distortion from slightly distorted square-planar to pseudo-tetrahedral. The cyclic voltammetric studies of 1-6 reveal that as the extent of the tetrahedral distortion of Cu(II) center increases on going from 1 to 5, the values of Cu(II)/Cu(I) potentials became more negative. The compounds have been oxidized electrochemically and chemically and the generated relatively stable uncoordinated phenoxyl [HL(x)](*+) and coordinated Cu(II)-phenoxyl radical [1-6](*+) species have been characterized by UV/vis and EPR spectroscopy." @default.
- W2166066714 created "2016-06-24" @default.
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- W2166066714 date "2010-07-01" @default.
- W2166066714 modified "2023-09-27" @default.
- W2166066714 title "Spectroscopic and electron-transfer reactivity studies of bulky bis(N-cycloalkyl-3,5-tBu2-salicylaldiminato)copper(II) complexes: Generation of uncoordinated and coordinated phenoxyl radicals" @default.
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- W2166066714 doi "https://doi.org/10.1016/j.saa.2010.02.016" @default.
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