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- W2166089999 abstract "Abstract Both steric and electronic factors appeared to be essential to the interaction of 2-aryl-1,3-indandiones with methemoglobin reductase. 2-Phenyl-1,3-indandione, 2-(3,5-di- tert .butylphenyl)-1,3-indandione and 2-(4-methoxyphenyl)-1,3-indandione were found to be cofactors of the enzyme. By introducing electron-attracting substituents into the phenyl ring strong competitive inhibitors were obtained: 2-(3,5-dichlorophenyl)-1,3-indandione and 2-(3,5-di-trifluoromethylphenyl)-1,3-indandione. Two ortho-substituted derivatives, 2-(2,6-dimethylphenyl)-1,3-indandione and 2-(2,4,6-trimethylphenyl)-1,3-indandione, had no effect at all on the reduction. The anti-inflammatory activities of 2-aryl-1,3-indandiones, as determined in a carrageenan oedema test, showed no relationship to the interaction with the enzyme." @default.
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- W2166089999 date "1978-03-01" @default.
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- W2166089999 title "Effects of 2-aryl-1,3-indandiones on the reduction of 2,6-dichlorophenol indophenol by methemoglobin reductase" @default.
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- W2166089999 doi "https://doi.org/10.1016/0006-2952(78)90422-7" @default.
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