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- W2166097984 endingPage "3072" @default.
- W2166097984 startingPage "3053" @default.
- W2166097984 abstract "We extend the SAFT‐VR+DE equation of state to describe 19 aqueous electrolyte solutions with both a fully dissociated and a partially dissociated model. The approach is found to predict thermodynamic properties such as the osmotic coefficient, water activity coefficient, and solution density, across different salt concentrations at room temperature and pressure in good agreement with experiment using only one or two fitted parameters. At higher temperatures and pressures, without any additional fitting, the theory is found to be in qualitative agreement with experimental mean ionic activities and osmotic coefficients. The behavior of the dielectric constant as a function of salt concentration is also reported for the first time using a statistical associating fluid theory (SAFT)‐based equation of state. At high salt concentrations, the stronger electrostatic interactions between the ionic species due to the dielectric decrement, is captured through the inclusion of ion association. © 2015 American Institute of Chemical Engineers AIChE J , 61: 3053–3072, 2015" @default.
- W2166097984 created "2016-06-24" @default.
- W2166097984 creator A5014971897 @default.
- W2166097984 creator A5016223283 @default.
- W2166097984 creator A5049224608 @default.
- W2166097984 creator A5072586806 @default.
- W2166097984 date "2015-08-07" @default.
- W2166097984 modified "2023-10-11" @default.
- W2166097984 title "Predicting the thermodynamic properties and dielectric behavior of electrolyte solutions using the SAFT‐VR+DE equation of state" @default.
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