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• W2166144314 abstract "Abstract The defect structure of non-stoichiometric strontium titanate thin films epitaxially grown on SrTiO3(100) substrates by pulsed-laser deposition was studied using transmission electron microscopy and X-ray diffraction. The A-site-excess SrTiO3 thin film adopted a completely unrelaxed pseudomorphic perovskite structure with an enlarged lattice parameter normal to the surface. Excess SrO was accommodated as Ruddlesden-Popper planar faults showing a peculiar three-dimensional mosaic structure, without forming secondary phases or dislocations due to non-stoichiometry. Biaxial compressive stress induced by lattice mismatch between the film and substrate was estimated at 9,7 GPa. Such a highly strained film is attributable to planar fault formation, which increases the cell volume and suppresses misfit dislocations. The B-site-excess SrTiO3 thin-film microstructure consisted of crystalline SrTiO3 and amorphous TiO2-rich phases. The slight increase in the lattice parameter normal to the surface and crystallographic shear structure with a TiO2 double layer suggest the low solubility of excess TiO2." @default.
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• W2166144314 date "2000-03-01" @default.
• W2166144314 modified "2023-09-26" @default.
• W2166144314 title "Defect structure in homoepitaxial non-stoichiometric strontium titanate thin films" @default.
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• W2166144314 doi "https://doi.org/10.1080/01418610008212072" @default.
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