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- W2166341834 abstract "Abstract Chiral CuF-catalyzed asymmetric allylation of ketones and ketimines is described. Nucleophile activation via transmetallation (allylboronate to allylcopper), which is facilitated by a cocatalyst [La(O i Pr) 3 or LiO i Pr], is key for these reactions. A CuOTf-3KO t Bu-DUPHOS complex is a comparably effective catalyst that reduces the required amount of chiral phosphines." @default.
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- W2166341834 date "2008-01-01" @default.
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- W2166341834 title "Cu(I)-catalyzed asymmetric allylation of ketones and ketimines" @default.
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- W2166341834 doi "https://doi.org/10.1351/pac200880051055" @default.
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