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• W2166457130 abstract "Colloidal solutions of iridium oxide hydrate (IrO 2 ·nH 2 O) were formed using porphyrin stabilizers bearing malonate-like functional groups at each of the four meso positions of the porphyrin ring. Cyclic voltammetry and monitoring of solution oxygen concentrations under constant applied potential demonstrated the electrochemical catalytic activity of the porphyrin–IrO 2 ·nH 2 O complexes for the oxidation of water to oxygen. Quenching of the porphyrin fluorescence in the complex implies strong interaction between the porphyrin and the IrO 2 ·nH 2 O. These results mark a step toward developing a porphyrin-based photoanode for use in a photoelectrochemical water-splitting cell." @default.
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• W2166457130 date "2011-02-01" @default.
• W2166457130 modified "2023-10-12" @default.
• W2166457130 title "A porphyrin-stabilized iridium oxide water oxidation catalyst" @default.
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• W2166457130 doi "https://doi.org/10.1139/v10-118" @default.
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