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- W2166506558 abstract "Head-to-head poly(vinyl cyclohexane) (H-H PVCH) was prepared from 2,3-diphenylbutadiene, which was polymerized by radical, 1,4 polymerization to poly(2,3-diphenylbutadiene) and then catalytically hydrogenated to H-H PVCH, H-H PVCH was also prepared by catalytic hydrogenation of H-H polystyrene (PS). The catalytic hydrogenations were carried out at an initial hydrogen pressure of 2000 psi and a temperature of 200°C. Some chemical, physical, and thermal properties of H-H PVCH were investigated and compared with the properties of atactic and isotactic head-to-tail (H-T) PVCH. The glass transition temperature of the H-H polymer was found to be 50°C lower than that of the atactic H-T polymer which indicates that the backbone chain has more flexibility. Both H-H and H-T PVCH showed comparable thermal stability. The temperature of the maximum rate of thermal degradation by differential thermogravimetric analysis was approximately 40°C higher than that of the corresponding polystyrenes." @default.
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- W2166506558 date "2007-03-08" @default.
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- W2166506558 title "Preparation and characterization of head-to-head polymers. VIII. Head-to-head poly(vinyl cyclohexane)" @default.
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- W2166506558 doi "https://doi.org/10.1002/polc.5070630127" @default.
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