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- W2166518653 abstract "The observation of a single exchange-narrowed E.P.R. line in [NiCl2-(diars)2]Cl, a monoclinic crystal with two magnetically inequivalent sites, is shown to be due to g-averaging and hence the concentration dependence of the g-tensor is explained. The lineshape analysis and the angular dependent linewidth data are used to evaluate various Fourier components of the spin-correlation function using Kubo-Tomita theory. The total linewidth is partitioned into secular and non-secular contributions of the broadening mechanisms—dipolar and hyperfine interactions. The angular dependence of the “10/3 effect” observed in X- and Q-bands could not be predicted by either the Blume-Hubbard or the Anderson-Weiss model. In the J regime [ ≈ 12 500 G or 3200 G > ≈ 700 G > dipolar, hyperfine ≈ 70 G] of [NiCl2(diars)2]Cl there is paucity of both experimental and theoretical studies." @default.
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- W2166518653 date "1984-05-01" @default.
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- W2166518653 title "The effect of weak exchange interaction on electron paramagnetic resonance in dichloro bis-<i>o</i>-phenylene bis-dimethyl arsino nickelate(III) chloride" @default.
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- W2166518653 doi "https://doi.org/10.1080/00268978400101061" @default.
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