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- W2166544324 abstract "calated between the M–Al–OH sheets are layers of (SO4) tetrahedra and (H2O) groups. All H atoms of (OH) and (H2O) groups were located, and details of hydrogen bonding are discussed. The structure of “nickelalumite” is similar to those of alvanite, ZnAl4(VO3)2(OH)12(H2O)2, and ankinovichite, NiAl4(VO3)2(OH)12(H2O)2, and stoichiometry and cell dimensions suggest that mbobomkulite and hydrombobomkulite also are related to “nickelalumite”. All structures are based on a positively charged sheets of octahedra of the form [ M 2+ M 3+ 4 (OH)12] 2+ that are intercalated with interstitial complexes of oxyanions and (H2O) groups. The Lewis acidity of the structural unit is 0.167 vu, and the character of the interstitial complexes is constrained by the valencesum rule of bond-valence theory. Possible interstitial oxyanions are (SO4) 2– , (NO3) 1– 2 and [VO3] 1– 2, whereas (SiO4) 4– , (BO3) 3– 2, (PO4) 3– and (BO4) 5– have Lewis basicities that are too high and hence cannot form “nickelalumite”-type structures." @default.
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- W2166544324 date "2005-10-01" @default.
- W2166544324 modified "2023-09-30" @default.
- W2166544324 title "THE CRYSTAL CHEMISTRY OF THE NICKELALUMITE-GROUP MINERALS" @default.
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- W2166544324 doi "https://doi.org/10.2113/gscanmin.43.5.1511" @default.
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