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- W2166683269 abstract "In Part ΙΙΙ of these studies, in which a number of isomorphous paradibromobenzenesulphonates of the rare earth metals (La, Ce, Nd, Pr, Gd, Sm) are described crystallographically,* the conclusion was arrived at that in these salts three of the benzenesulphonic groups, together with 9 or 12 molecules of water, are disposed symmetrically in a plane around a central atom of the tervalent metal. Molecular units presumably of this kind are packed together in a structure one dimension of which corresponds to the thickness of a single benzene complex observed in numerous substituted benzene derivatives, such as diiodobenzene, for example; as was pointed out, the salts under consideration may be regarded, in fact, as derived from benzene merely by the pushing apart of the zigzag columns of carbon domains, depicted by Barlow and Pope as characteristic of the hydrocarbon, in such manner as to allow of the introduction of the substituting groups present in the sulphonate in addition to benzene. In view of this result, it was desirable to determine the crystalline structure of the acid from which the salts were derived as well as of salts containing metals of other degrees of valency. Numerous unsuccessful attempts were made to obtain measurable crystals of the paradibromo-acid; ultimately, good crystals were secured of the corresponding dichloro-acid and of its lanthanum, neodymium and praseodymium salts." @default.
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- W2166683269 date "1913-09-22" @default.
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- W2166683269 title "Morphological studies in the benzene series. IV. —The crystalline form of sulphonates in relation to their molecular structure" @default.
- W2166683269 doi "https://doi.org/10.1098/rspa.1913.0085" @default.
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