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• W2166993615 abstract "A direct method to construct 2-oxazolines and 2-thiazolines from corresponding allylic amides and thioamides is reported. The redox-neutral intramolecular hydrofunctionalization is enabled by a dual catalyst system comprised of the 9-mesityl-N-methyl acridinium tetrafluoroborate and phenyl disulphide and exhibits complete selectivity for the anti-Markovnikov regioisomeric products. The cyclization of allylic thioamides is postulated to operate via a modified mechanism in which oxidation of the thioamide, rather than the alkene, is responsible for the observed reactivity." @default.
• W2166993615 created "2016-06-24" @default.
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• W2166993615 date "2015-01-01" @default.
• W2166993615 modified "2023-10-07" @default.
• W2166993615 title "Divergent regioselectivity in photoredox-catalyzed hydrofunctionalization reactions of unsaturated amides and thioamides" @default.
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• W2166993615 doi "https://doi.org/10.1039/c4sc02331e" @default.
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