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• W2167111330 startingPage "656" @default.
• W2167111330 abstract "ESIPT and ESPT are the only photochemical deactivation pathways of the singlet excited states of 2-, 3- and 4-(2’-hydroxyphenyl)pyridines (1a–c). Due to the existence of an intramolecular hydrogen bond in 2-(2’-hydroxyphenyl)pyridine (1a), ESIPT leads only to protonation of the pyridine nitrogen. On the other hand, the singlet excited states of 3- and 4-(2’-hydroxyphenyl)pyridine (1b,c) undergo protonation of both nitrogen and carbon atoms of the pyridine ring, via ESIPT or ESPT. The extent of ESIPT to carbon (as measured by extent of deuterium incorporation) can be controlled by the amount of water in the solvent system." @default.
• W2167111330 created "2016-06-24" @default.
• W2167111330 creator A5084181692 @default.
• W2167111330 creator A5085433318 @default.
• W2167111330 date "2006-07-01" @default.
• W2167111330 modified "2023-09-27" @default.
• W2167111330 title "Excited state proton transfer (ESPT) from phenol to nitrogen and carbon in (2-hydroxyphenyl)pyridines" @default.
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• W2167111330 doi "https://doi.org/10.1039/b600826g" @default.
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