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- W2167219933 abstract "A novel compound (H2en)5[CoMo12O50P8(OH)12] ·2H2O (1) (en = H2NCH2CH2NH2) has been hydrothermally synthesized and characterized by elemental analyses, IR, EPR, XPS spectra and single-crystal X-ray diffraction analyses. Compound 1 crystallizes in a triclinic system, space group Pi, with a = 1.1863(2) nm, b = 1.3361(3) nm, c = 1.3783(3) nm, a = 88.13(3)°, β = 70.09(3)°, γ = 65.24(3)°, V = 1.8497(6) mn3, and R = 0.0417. The basic building blocks of compound 1 are|Mo6P4 [clusters forming dimers through the|CoO6] octahedra. Compound 1 exhibits an unusual three-dimensional framework with tunnels owing to the extensive hydrogen bonding interactions between the dimers and H2en." @default.
- W2167219933 created "2016-06-24" @default.
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- W2167219933 date "2010-08-26" @default.
- W2167219933 modified "2023-09-27" @default.
- W2167219933 title "A Novel Three-dimensional Framework with Tunnels Based on the Cobalt-containing Molybdenum Phosphate Moieties" @default.
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- W2167219933 doi "https://doi.org/10.1002/cjoc.20030210509" @default.
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