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- W2167444995 abstract "A brief description of a high-resolution circular dichrograph is given. For MCD measurements a 0·52 T permanent magnet and silica flow tubes are used to obtain data with variable sample temperatures as low as 4·2 K. The MCD results provide an unambiguous assignment of the 4 A 1g and 4 Eg a states of Mn2+ in KMgF3 and KZnF3. The 4 Eg a state lies 90–100 cm-1 below 4 A 1g . A theoretical analysis of the MCD results confirms the assignment of the 4 A 1g state, while an analysis of the spin-orbit splitting of the 4 Eg a state has been carried out using all 252 |αLSJMJ > functions of the d5 configuration. The observed positions of the three components of 4 Eg a are accurately accounted for by Dq values appropriate to KMgF3 and KZnF3 and a spin-orbit coupling constant of approximately 300 cm-1." @default.
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- W2167444995 date "1974-03-01" @default.
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- W2167444995 title "High-resolution MCD spectroscopy of transition metal ions in fluoride crystals" @default.
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- W2167444995 doi "https://doi.org/10.1080/00268977400100501" @default.
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