FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2167525848> ?p ?o ?g. }

• W2167525848 endingPage "2585" @default.
• W2167525848 startingPage "2578" @default.
• W2167525848 abstract "The reaction between aqueous manganese(III) ions, , and (H2O)5CrOO2+ has a 1 : 1 stoichiometry and generates and O2 as products. The mixed second-order rate constant exhibits an [H+] dependence that identifies the hexaaquamanganese ion as the reactive form at 0.5 ≤ [H+] ≤ 3.0 mol L−1, k H = 350 ± 10 (mol L−1)−1 s−1. The reactivity of (H2O)5MnOH2+ is negligible under these conditions, most likely because the much lower reduction potential of this hydrolytic form results in unfavorable thermodynamics for the overall reaction. also oxidizes a benzylchromium ion, (H2O)5CrCH2Ph2+, with a rate constant k = 273 ± 13 (mol L−1)−1 s−1 in 3.0 mol L−1 HClO4. The reaction has a 2 : 1 []/[(H2O)5CrCH2Ph2+] stoichiometry and generates benzyl alcohol as the sole organic product. The data are consistent with oxidative homolysis which generates benzyl radicals followed by rapid oxidation of the radicals with the second equivalent of . The unexpected similarity between the rate constants for the oxidation of (H2O)5CrOO2+ and (H2O)5CrCH2Ph2+ is discussed." @default.
• W2167525848 created "2016-06-24" @default.
• W2167525848 creator A5020163825 @default.
• W2167525848 creator A5023945642 @default.
• W2167525848 creator A5031611215 @default.
• W2167525848 creator A5056279624 @default.
• W2167525848 creator A5088484225 @default.
• W2167525848 date "2010-07-06" @default.
• W2167525848 modified "2023-09-25" @default.
• W2167525848 title "Mechanism of oxidation of alkyl and superoxo complexes of chromium(III) by aquamanganese(III) ions" @default.
• W2167525848 cites W1983948540 @default.
• W2167525848 cites W1995753880 @default.
• W2167525848 cites W1997376774 @default.
• W2167525848 cites W1997928225 @default.
• W2167525848 cites W2028171470 @default.
• W2167525848 cites W2037439880 @default.
• W2167525848 cites W2049330893 @default.
• W2167525848 cites W2053441432 @default.
• W2167525848 cites W2059343227 @default.
• W2167525848 cites W2089206549 @default.
• W2167525848 cites W2090047189 @default.
• W2167525848 cites W2319590886 @default.
• W2167525848 cites W2950136509 @default.
• W2167525848 doi "https://doi.org/10.1080/00958972.2010.498510" @default.
• W2167525848 hasPublicationYear "2010" @default.
• W2167525848 type Work @default.
• W2167525848 sameAs 2167525848 @default.
• W2167525848 citedByCount "0" @default.
• W2167525848 crossrefType "journal-article" @default.
• W2167525848 hasAuthorship W2167525848A5020163825 @default.
• W2167525848 hasAuthorship W2167525848A5023945642 @default.
• W2167525848 hasAuthorship W2167525848A5031611215 @default.
• W2167525848 hasAuthorship W2167525848A5056279624 @default.
• W2167525848 hasAuthorship W2167525848A5088484225 @default.
• W2167525848 hasConcept C121332964 @default.
• W2167525848 hasConcept C139066938 @default.
• W2167525848 hasConcept C142724271 @default.
• W2167525848 hasConcept C144082473 @default.
• W2167525848 hasConcept C145148216 @default.
• W2167525848 hasConcept C147789679 @default.
• W2167525848 hasConcept C148898269 @default.
• W2167525848 hasConcept C155647269 @default.
• W2167525848 hasConcept C161790260 @default.
• W2167525848 hasConcept C175689099 @default.
• W2167525848 hasConcept C178790620 @default.
• W2167525848 hasConcept C179104552 @default.
• W2167525848 hasConcept C184651966 @default.
• W2167525848 hasConcept C185592680 @default.
• W2167525848 hasConcept C204787440 @default.
• W2167525848 hasConcept C2776460118 @default.
• W2167525848 hasConcept C2776910235 @default.
• W2167525848 hasConcept C2780263894 @default.
• W2167525848 hasConcept C511782168 @default.
• W2167525848 hasConcept C528890316 @default.
• W2167525848 hasConcept C55904794 @default.
• W2167525848 hasConcept C62520636 @default.
• W2167525848 hasConcept C65024703 @default.
• W2167525848 hasConcept C71924100 @default.
• W2167525848 hasConcept C75473681 @default.
• W2167525848 hasConcept C90150868 @default.
• W2167525848 hasConcept C93391505 @default.
• W2167525848 hasConcept C94412978 @default.
• W2167525848 hasConceptScore W2167525848C121332964 @default.
• W2167525848 hasConceptScore W2167525848C139066938 @default.
• W2167525848 hasConceptScore W2167525848C142724271 @default.
• W2167525848 hasConceptScore W2167525848C144082473 @default.
• W2167525848 hasConceptScore W2167525848C145148216 @default.
• W2167525848 hasConceptScore W2167525848C147789679 @default.
• W2167525848 hasConceptScore W2167525848C148898269 @default.
• W2167525848 hasConceptScore W2167525848C155647269 @default.
• W2167525848 hasConceptScore W2167525848C161790260 @default.
• W2167525848 hasConceptScore W2167525848C175689099 @default.
• W2167525848 hasConceptScore W2167525848C178790620 @default.
• W2167525848 hasConceptScore W2167525848C179104552 @default.
• W2167525848 hasConceptScore W2167525848C184651966 @default.
• W2167525848 hasConceptScore W2167525848C185592680 @default.
• W2167525848 hasConceptScore W2167525848C204787440 @default.
• W2167525848 hasConceptScore W2167525848C2776460118 @default.
• W2167525848 hasConceptScore W2167525848C2776910235 @default.
• W2167525848 hasConceptScore W2167525848C2780263894 @default.
• W2167525848 hasConceptScore W2167525848C511782168 @default.
• W2167525848 hasConceptScore W2167525848C528890316 @default.
• W2167525848 hasConceptScore W2167525848C55904794 @default.
• W2167525848 hasConceptScore W2167525848C62520636 @default.
• W2167525848 hasConceptScore W2167525848C65024703 @default.
• W2167525848 hasConceptScore W2167525848C71924100 @default.
• W2167525848 hasConceptScore W2167525848C75473681 @default.
• W2167525848 hasConceptScore W2167525848C90150868 @default.
• W2167525848 hasConceptScore W2167525848C93391505 @default.
• W2167525848 hasConceptScore W2167525848C94412978 @default.
• W2167525848 hasIssue "14-16" @default.
• W2167525848 hasLocation W21675258481 @default.
• W2167525848 hasOpenAccess W2167525848 @default.
• W2167525848 hasPrimaryLocation W21675258481 @default.
• W2167525848 hasRelatedWork W1689466739 @default.
• W2167525848 hasRelatedWork W1989364830 @default.
• W2167525848 hasRelatedWork W2030375916 @default.
• W2167525848 hasRelatedWork W2034865712 @default.

• next