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• W2167577636 endingPage "4684" @default.
• W2167577636 startingPage "4677" @default.
• W2167577636 abstract "New data are presented for the room temperature, static compression of iron to 78 GPa with solid neon and argon as pressure‐transmitting media. X ray diffraction studies have been performed on a geophysically relevant material, for the first time to such pressures under quasihydrostatic conditions, in a diamond anvil cell. The hydrostatic technique leads to increased precision in the measurement of high pressures and has placed closer constraints on the equation of state of ε iron. From a linear least squares fit of a finite strain equation of state to the present data combined with earlier, low‐pressure data for metastable ε iron, the preferred values for the zero‐pressure isothermal bulk modulus, K 0 , and first pressure derivative, K 0 ′, are 192.7 (±9.0) GPa and 4.29 (±0.36), respectively. The zero‐pressure volume for the ε phase is 6.687 (±0.018) cm 3 /mol. On the basis of the pressure‐volume curve calculated from fits of the finite strain equation of state, ε iron appears to be less compressible under nonhydrostatic conditions, but the differences are within the error of the nonhydrostatic experiment. The results also confirm that the absence of a soft medium in static compression experiments with the diamond anvil cell results in an overestimate of the unit cell volume (measured with the incident X ray beam parallel to the load axis) for pressures calculated with the nonhydrostatic ruby calibration scale. It is found that for ε iron, substantial compensation for this nonhydrostatic effect is implicit in the nonhydrostatic ruby pressure scale up to intermediate strains. The hydrostatic data and the ε iron isotherm derived from shock wave experiments on iron samples are in very close agreement." @default.
• W2167577636 created "2016-06-24" @default.
• W2167577636 creator A5018374386 @default.
• W2167577636 creator A5065990977 @default.
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• W2167577636 date "1986-04-10" @default.
• W2167577636 modified "2023-10-17" @default.
• W2167577636 title "Static compression of iron to 78 GPa with rare gas solids as pressure‐transmitting media" @default.
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• W2167577636 doi "https://doi.org/10.1029/jb091ib05p04677" @default.
• W2167577636 hasPublicationYear "1986" @default.
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