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• W2167605685 abstract "The asymmetry in angular rigidity of the proton donor and proton acceptor of hydrogen-bonded hydrogen fluoride binary complexes is investigated. The intermolecular bending frequency of HF, as the proton donor, is linearly proportional to the square root of the dissociation energy, whereas that of the proton acceptor is always much lower. The asymmetry, measured by the ratio of bending elastic constants of HF to that of the proton acceptor, is generally >2, and varies pronouncedly with the acceptors reaching values >20. Molecules with nitrogen as the bridged acceptor atom show an angular rigidity nearly one order of magnitude greater than the group with oxygen as the proton acceptor." @default.
• W2167605685 created "2016-06-24" @default.
• W2167605685 creator A5037649483 @default.
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• W2167605685 date "2005-08-22" @default.
• W2167605685 modified "2023-09-23" @default.
• W2167605685 title "Asymmetry in angular rigidity of hydrogen-bonded complexes" @default.
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• W2167605685 doi "https://doi.org/10.1073/pnas.0506325102" @default.
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