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• W2167705295 abstract "The noncovalent synthesis of layer-block metallodendrimers containing hydrophobic shells of covalent dendritic wedges at the periphery is described. Starting from first- and second-generation Fréchet wedges having phosphines at their focal point, convergent dendritic growth yields third- and fourth-generation metallodendrimers in which the coordination of nitriles, pyridines, and phosphines to SCS Pd(II) pincers is used as the assembly motif. In this convergent growth, the number of terminal hydrophobic phosphine wedges increases with generation. The solubility of the dendritic structures in apolar organic solvents such as chloroform and dichloromethane increases accordingly, in contrast to previously reported metallodendrimers. All dendritic structures were characterized by (1)H and (31)P NMR spectroscopy, elemental analysis, and MALDI-TOF mass spectrometry." @default.
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• W2167705295 date "2001-06-01" @default.
• W2167705295 modified "2023-09-25" @default.
• W2167705295 title "Convergent Synthesis of Noncovalent Metallodendrimers Containing Hydrophobic Dendrons at the Periphery" @default.
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• W2167705295 doi "https://doi.org/10.1021/jo0101757" @default.
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