FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2167889600> ?p ?o ?g. }

• W2167889600 endingPage "134" @default.
• W2167889600 startingPage "127" @default.
• W2167889600 abstract "Thermally reversible polymers with relatively high glass transition temperatures (Tg) are difficult to prepare but very interesting from an application point of view. In this work we present a novel reversible thermoset with tunable Tg based on chemical modification of aliphatic polyketones (PK) into the corresponding derivatives containing furan (PK–FA) and/or amine (PK–DAP) groups along the backbone. The furan moieties allow thermal setting of the polymer by the Diels–Alder (DA) and retro-DA sequence with bis-maleimide (bis-Ma), while amine moieties allow tuning the hydrogen bonding density. By this combined approach, it is possible to synthesize well-defined thermosets with a wider Tg window with respect to PK–FA alone. Indeed, after several heating cycles, the material showed essentially the mechanical properties of the original even after the samples were broken and thermally reshaped. The incorporation of amine moieties at 20–60% conversion of the 1,4-dicarbonyl units along the PK-backbone significantly increased the Tg window from 100 °C to 185 °C. However, after each heating cycle the Tg of the material, detected as tan (δ) in DMTA measurements, continued to increase probably due to imine group formation between unreacted carbonyl and amine groups. Despite this limitation, the studied system still displays re-workability up to three thermal cycles and constitutes a proof of principle for the proposed approach, i.e. combination of Diels–Alder and hydrogen bonding groups towards higher Tg materials." @default.
• W2167889600 created "2016-06-24" @default.
• W2167889600 creator A5057519109 @default.
• W2167889600 creator A5084738855 @default.
• W2167889600 creator A5090097550 @default.
• W2167889600 date "2014-01-01" @default.
• W2167889600 modified "2023-10-17" @default.
• W2167889600 title "Reversible polymer networks containing covalent and hydrogen bonding interactions" @default.
• W2167889600 cites W1963987806 @default.
• W2167889600 cites W1966731690 @default.
• W2167889600 cites W1966745136 @default.
• W2167889600 cites W1967903036 @default.
• W2167889600 cites W1972675654 @default.
• W2167889600 cites W1975576798 @default.
• W2167889600 cites W1976755375 @default.
• W2167889600 cites W1980533467 @default.
• W2167889600 cites W1982143398 @default.
• W2167889600 cites W1984744050 @default.
• W2167889600 cites W1986921200 @default.
• W2167889600 cites W1987209504 @default.
• W2167889600 cites W1990089587 @default.
• W2167889600 cites W1990452960 @default.
• W2167889600 cites W1995444055 @default.
• W2167889600 cites W1997293796 @default.
• W2167889600 cites W1998924519 @default.
• W2167889600 cites W2018899687 @default.
• W2167889600 cites W2028175598 @default.
• W2167889600 cites W2029080113 @default.
• W2167889600 cites W2030656008 @default.
• W2167889600 cites W2035590412 @default.
• W2167889600 cites W2043108127 @default.
• W2167889600 cites W2047798829 @default.
• W2167889600 cites W2052886839 @default.
• W2167889600 cites W2056777003 @default.
• W2167889600 cites W2064692473 @default.
• W2167889600 cites W2078050686 @default.
• W2167889600 cites W2081200140 @default.
• W2167889600 cites W2095325668 @default.
• W2167889600 cites W2137391977 @default.
• W2167889600 cites W2150916092 @default.
• W2167889600 cites W2158619399 @default.
• W2167889600 cites W2164526292 @default.
• W2167889600 cites W2164937094 @default.
• W2167889600 cites W2312920589 @default.
• W2167889600 cites W3026119829 @default.
• W2167889600 doi "https://doi.org/10.1016/j.eurpolymj.2013.10.014" @default.
• W2167889600 hasPublicationYear "2014" @default.
• W2167889600 type Work @default.
• W2167889600 sameAs 2167889600 @default.
• W2167889600 citedByCount "51" @default.
• W2167889600 countsByYear W21678896002014 @default.
• W2167889600 countsByYear W21678896002015 @default.
• W2167889600 countsByYear W21678896002016 @default.
• W2167889600 countsByYear W21678896002017 @default.
• W2167889600 countsByYear W21678896002018 @default.
• W2167889600 countsByYear W21678896002019 @default.
• W2167889600 countsByYear W21678896002020 @default.
• W2167889600 countsByYear W21678896002021 @default.
• W2167889600 countsByYear W21678896002022 @default.
• W2167889600 countsByYear W21678896002023 @default.
• W2167889600 crossrefType "journal-article" @default.
• W2167889600 hasAuthorship W2167889600A5057519109 @default.
• W2167889600 hasAuthorship W2167889600A5084738855 @default.
• W2167889600 hasAuthorship W2167889600A5090097550 @default.
• W2167889600 hasConcept C112887158 @default.
• W2167889600 hasConcept C122865956 @default.
• W2167889600 hasConcept C131779359 @default.
• W2167889600 hasConcept C161790260 @default.
• W2167889600 hasConcept C171359207 @default.
• W2167889600 hasConcept C178790620 @default.
• W2167889600 hasConcept C180577832 @default.
• W2167889600 hasConcept C185592680 @default.
• W2167889600 hasConcept C188027245 @default.
• W2167889600 hasConcept C192562407 @default.
• W2167889600 hasConcept C2776573223 @default.
• W2167889600 hasConcept C2778659115 @default.
• W2167889600 hasConcept C2780105360 @default.
• W2167889600 hasConcept C32909587 @default.
• W2167889600 hasConcept C521977710 @default.
• W2167889600 hasConceptScore W2167889600C112887158 @default.
• W2167889600 hasConceptScore W2167889600C122865956 @default.
• W2167889600 hasConceptScore W2167889600C131779359 @default.
• W2167889600 hasConceptScore W2167889600C161790260 @default.
• W2167889600 hasConceptScore W2167889600C171359207 @default.
• W2167889600 hasConceptScore W2167889600C178790620 @default.
• W2167889600 hasConceptScore W2167889600C180577832 @default.
• W2167889600 hasConceptScore W2167889600C185592680 @default.
• W2167889600 hasConceptScore W2167889600C188027245 @default.
• W2167889600 hasConceptScore W2167889600C192562407 @default.
• W2167889600 hasConceptScore W2167889600C2776573223 @default.
• W2167889600 hasConceptScore W2167889600C2778659115 @default.
• W2167889600 hasConceptScore W2167889600C2780105360 @default.
• W2167889600 hasConceptScore W2167889600C32909587 @default.
• W2167889600 hasConceptScore W2167889600C521977710 @default.
• W2167889600 hasLocation W21678896001 @default.
• W2167889600 hasOpenAccess W2167889600 @default.
• W2167889600 hasPrimaryLocation W21678896001 @default.
• W2167889600 hasRelatedWork W1994347396 @default.

• next