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- W2167912345 abstract "Abstract The synthesis of face‐to‐face meso ‐substituted bis(corrole) systems was revisited. By using a new synthetic pathway, the reaction was generalized to any type of linker and the yield was considerably increased. The dyads were obtained in yields up to 20 % from a dialdehyde linker and dipyrromethane in a one‐step reaction. The best reaction conditions required a decreased amount of TFA catalyst (1.4 equiv.) and a large excess of dipyrromethane (up to 8 equiv). Under these conditions, four bis(corrole)s linked by 2,2′‐diphenyl ether, 9,9‐dimethylxanthene, anthracene, and dibenzofuran spacers were synthesized.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)" @default.
- W2167912345 created "2016-06-24" @default.
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- W2167912345 date "2008-02-13" @default.
- W2167912345 modified "2023-10-09" @default.
- W2167912345 title "Efficient Two‐Step Synthesis of Face‐to‐Face <i>meso</i>‐Substituted Bis(corrole) Dyads" @default.
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- W2167912345 doi "https://doi.org/10.1002/ejoc.200700985" @default.
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