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- W2167940033 abstract "In peptide synthesis, hydrazides are important intermediates for the azide coupling method. A hydrazide is converted to the corresponding azide in the presence of an acid and a nitrite. When acetic acid (or formic acid) is used as the acid, partial acetylation (or formylation) of the hydrazide occurs as a side reaction. Formylation of the hydrazide is much faster than acetylation. Removal of the formyl group on the hydrazide with hydrazine and hydroxylamine was studied. The rate of deformylation with hydrazine treatment is faster than that with hydroxylamine treatment." @default.
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- W2167940033 date "2002-01-01" @default.
- W2167940033 modified "2023-10-17" @default.
- W2167940033 title "Acylation of Hydrazides with Acetic Acid and Formic Acid." @default.
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- W2167940033 doi "https://doi.org/10.1248/cpb.50.140" @default.
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