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- W2168108465 abstract "An experimental kinetic study of the silver catalysed oxidation of methanol, together with an independent infrared spectroscopic examination of adsorbed species under reaction conditions reveals that the product formaldehyde is form ed by gas-phase methanol interacting with dissociatively adsorbed oxygen. Intermediate surface species formed are CH 3 O– and –O–CH 2 –O– and appear to be important precursors to product formation. A kinetic two-step mode) formulated on the basis of the experimental evidence gives a good numerical fit to the experimental data. An elementary reactor model incorporating the same kinetic model underestimates conversion and overestimates exit temperature when compared with actual performance data." @default.
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- W2168108465 date "1985-05-08" @default.
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- W2168108465 title "The catalytic oxidation of methanol" @default.
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- W2168108465 doi "https://doi.org/10.1098/rspa.1985.0054" @default.
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