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• W2168156710 abstract "Film growth by physical vapor deposition on rotating substrates is modeled via a kinetic Monte Carlo algorithm on a two-dimensional hexagonal lattice. The motivation is to provide insight on the evolution of porosity during the deposition of thermal barrier coatings (TBCs). The model is implemented on an atomic scale that incorporates the effect of surface diffusion as well as the interplay between surface topography and the changing vapor incidence angle. It is shown that substrate rotation generates voids with a periodicity dependent on the amount of material deposited per revolution. The onset of pore formation and morphology of the pores are linked to the presence of shadowing features on the surface, either in the form of stochastic or crystallographic peaks and valleys evolving during columnar growth, or pre-existing roughness typical of polycrystalline oxide substrates. In addition, various forms of anisotropy develop in the microstructure as a result of the “sunrise–sunset” pattern of vapor incidence characteristic of TBC deposition on, for example, turbine airfoils. Comparison with observations on actual TBCs reveals that the simulations, in spite of their simplicity, capture several key microstructural features characteristic of these complex films." @default.
• W2168156710 created "2016-06-24" @default.
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• W2168156710 date "2005-01-01" @default.
• W2168156710 modified "2023-10-01" @default.
• W2168156710 title "A kinetic Monte Carlo simulation of film growth by physical vapor deposition on rotating substrates" @default.
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• W2168156710 doi "https://doi.org/10.1016/j.msea.2004.09.015" @default.
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