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• W2168304899 abstract "The pH-activated E/Z isomerization of a series of hydrazone-based systems having different functional groups as part of the rotor (R = COMe, CN, Me, H), was studied. The switching efficiency of these systems was compared to that of a hydrazone-based molecular switch (R = COOEt) whose E/Z isomerization is fully reversible. It was found that the nature of the R group is critical for efficient switching to occur; the R group should be a moderate H-bond acceptor in order to (i) provide enough driving force for the rotor to move upon protonation, and (ii) stabilize the obtained Z configuration, to achieve full conversion." @default.
• W2168304899 created "2016-06-24" @default.
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• W2168304899 date "2012-06-13" @default.
• W2168304899 modified "2023-09-30" @default.
• W2168304899 title "The importance of the rotor in hydrazone-based molecular switches" @default.
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• W2168304899 doi "https://doi.org/10.3762/bjoc.8.98" @default.
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