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- W2168360153 abstract "A copper(II) complex of 2-hydroxyiminopropanoic acid (hpa) has been prepared and characterized by X-ray analysis, infrared, Raman and EPR spectra. The bidentate hpa ligand chelates the copper ion through the oxime nitrogen and the carboxyl oxygen to form an anionic bis-complex. An intramolecular H-bond stabilizes the two ligands in a cis planar coordination. Equilibrium geometries, harmonic vibrational frequencies, infrared and Raman intensities were calculated for hpa and its copper(II) complex by using DFT (B3LYP) and Hartree–Fock methods with 6-31G(d) and Lanl2DZ basis sets. The computed properties are compared to the experimental values." @default.
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- W2168360153 date "2004-01-01" @default.
- W2168360153 modified "2023-10-17" @default.
- W2168360153 title "Solid state study of the copper(<scp>ii</scp>) complex of 2-hydroxyiminopropanoic acid" @default.
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- W2168360153 doi "https://doi.org/10.1039/b307066m" @default.
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