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- W2168367045 abstract "Organomolybdenum and Organotungsten Reagents, III. — Selective, Nonbasic Carbonylmethylenation Reagents from MoOCl3(THF)2 and MoOCl4: Formation, Thermolability, Structure From the family of more than 20 carbonylolefinating μ-methylene molybdenum and tungsten complexes[1,2] the reagent “3”, obtained in solution by treatment of MoOCl3(THF)2 with two equivalents of methyllithium, is probably the most favorable one for chemoselective carbonylolefination reactions. As judged by the 13C- and 1H-NMR spectra the reagent is not a single species, but a mixture of either isomeric 1,3-dioxo-1,3-dimolybda(V)cyclobutane complexes 3, differing in the position of the ligands Cl, O, and THF at the molybdenum atoms, or of oligomers of 3. — Treatment of MoOCl4 with two equivalents of methyllithium gave a carbonylolefinating reagent “4” which, according to NMR data, consists of isomeric or oligomeric 1,3-dioxo-1,3-dimolybda(VI)cyclobutane complexes 4. Both reagents are labile at room temperature, but differ from the classical carbonylolefinating reagents by an acidic rather than a basic character, resistance to hydroxy groups, and high selectivity." @default.
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- W2168367045 title "Organomolybdän‐ und Organowolfram‐;Reagenzien, III. Chemoselektive, nichtbasische Carbonylmethylenierungs‐;Reagenzien aus MoOCl <sub>3</sub> (THF) <sub>2</sub> und MoOCl <sub>4</sub> : Bildung, Thermolabilität, Struktur" @default.
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- W2168367045 doi "https://doi.org/10.1002/cber.19931260114" @default.
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