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- W2168397730 abstract "Circular dichroism and u.v. spectra of tris(ethylenediamine)cobalt(III), [Co en3]3+, ions in aqueous solutions of various polyelectrolytes are reported. The results indicate that the c.d. of the CoIII complex ions is diversely changed upon interaction with polyanions which differ in chemical constitution and also with polyanions different only in chain stereoregularity. In the case of poly(methacrylic acid) it is also shown that the optical activity of [Co en3]3+ ions varies discontinuously with increasing the degree of neutralisation, α, of the polyacid in the interval of α values in which poly(methacrylic acid) chains undergo a conformational transition." @default.
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- W2168397730 date "1968-01-01" @default.
- W2168397730 modified "2023-09-27" @default.
- W2168397730 title "Specificity in the interaction of asymmetric tris(ethylenediamine)cobalt(III) ions with different polyanions in aqueous solution. A circular dichroism and ultraviolet spectral investigation" @default.
- W2168397730 doi "https://doi.org/10.1039/j19680002175" @default.
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