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- W2168425919 abstract "Dibenzosemibullvalene and its dicarbomethoxy derivative react with dicarbonylchlororhodium(I) dimers to yield complexes consisting of a novel Rh(III)-containing 4-membered heterocyclic ring system as the initial products. Upon reaction with carbon monoxide or at higher reaction temperature, CO-insertion occurs to give thermodynamically more stable metal acyl derivatives. The presence of the two strongly electron withdrawing substituents in the dicarbomethoxy derivatives (i) greatly reduces the reaction rate in complex formation, and (ii) readily regenerates the free organic ligand from the metal acyl complexes." @default.
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- W2168425919 date "1976-02-01" @default.
- W2168425919 modified "2023-09-23" @default.
- W2168425919 title "Reaction of dibenzosemibullvalenes with Rh(CO)2Cl2. Isolation of 4-membered rhodium(III)-containing heterocycles" @default.
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- W2168425919 doi "https://doi.org/10.1016/s0022-328x(00)88965-2" @default.
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