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• W2168434919 abstract "A new series of diorganotin complexes of the type R2SnL (L1: N-(2-hydroxy-5-chlorophenyl)- 3-ethoxysalicylideneimine, R = Me, (Me2SnL1), R = n-Bu, (n-Bu2SnL1), R = Ph, (Ph2SnL1), L2: N-(2-hydroxy-4-nitro-5-chlorophenyl)-3-ethoxysalicylideneimine, R = Ph, Ph2SnL2, L3: N-(2-hydroxy-4-nitrophenyl)-3-methoxysalicylideneimine, R = Me, (Me2SnL3), R = n-Bu, (n-Bu2SnL3), L4: N-(2-hydroxy-4-nitrophenyl)-3-ethoxysalicylideneimine, R = Me, (Me2SnL4), R = n-Bu, (n-Bu2SnL4)) were synthesized and characterized by elemental analysis, infrared (IR), 1H, and 13C NMR mass spectroscopic techniques, and electrochemical measurements. Ph2SnL1 and Ph2SnL2 were also characterized by X-ray diffraction analysis and were found to show a fivefold C2NO2 coordination geometry nearly halfway between a trigonal bipyramidal and distorted square pyramidal arrangement. The CSnC angles in the complexes were calculated using Lockhart's equations with the 1J(117/119Sn-13C) and 2J(117/119Sn-1H) values from the 1H NMR and 13C NMR spectra. Biocidal activity tests against several micro-organisms and some fungi indicate that all the complexes are mildly active against Gram (+) bacteria and the fungi, A. niger and inactive against Gram (−) bacteria. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:373–385, 2010; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.20628" @default.
• W2168434919 created "2016-06-24" @default.
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• W2168434919 date "2010-01-01" @default.
• W2168434919 modified "2023-10-18" @default.
• W2168434919 title "Synthesis, characterization, and in vitro antimicrobial activities of organotin(IV) complexes of Schiff bases with ONO-type donor atoms" @default.
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• W2168434919 doi "https://doi.org/10.1002/hc.20628" @default.
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