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• W2168448001 abstract "Two Dy(III) complexes with benzoate derivative and 2,2′-bipyridine ligands, [Dy(2,4-DClBA)3bipy]2 and [Dy(o-MOBA)3bipy]2·4H2O (2,4-DClBA=2,4-dichlorobenzoate; o-MOBA=o-methoxybenzoate; bipy=2,2′-bipyridine), were prepared and characterized by elemental analysis, infrared spectra, ultraviolet spectra and thermogravimetry and differential thermogravimetry techniques. The thermal decomposition behavior of the two complexes under a static air atmosphere was discussed by thermogravimetry, differential thermogravimetry and infrared spectral techniques. The non-isothermal kinetics were investigated by using a double equal-double step method, a non-linear isoconversional integral method and a Starink method. The mechanism functions of the first decomposition step for [Dy(2,4-DClBA)3bipy]2 and the second decomposition step for [Dy(o-MOBA)3bipy]2·4H2O were determined. Meanwhile, the thermodynamic parameters (ΔHne;, ΔGne; and ΔSne;) and kinetic parameters (activation energy E and the pre-exponential factor A) for the two complexes were also calculated." @default.
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• W2168448001 date "2009-11-01" @default.
• W2168448001 modified "2023-09-25" @default.
• W2168448001 title "Synthesis and Thermal Decomposition Kinetics of Two Dy(III) Complexes with Benzoate Derivative and 2,2′-Bipyridine as Co-ligands" @default.
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• W2168448001 doi "https://doi.org/10.1002/cjoc.200990357" @default.
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