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- W2168613871 endingPage "57" @default.
- W2168613871 startingPage "42" @default.
- W2168613871 abstract "The effects of introducing ionic functionalities in phosphine ligands on the coordination chemistry of these ligands and the catalytic behavior of the corresponding metal complexes are reviewed. The steric and electronic consequences of such functionalizations are discussed. Apart from these steric and electronic effects, the presence of charged groups often leads to additional, supramolecular interactions that occur in the second coordination sphere of the metal complex, such as intramolecular, interligand hydrogen bonding and Coulombic repulsion. These interactions can significantly alter the behavior of the phosphine ligand in question. Such effects have been observed in phosphine-metal association/dissociation equilibria, ligand substitution reactions, and stereoisomerism in phosphine-metal complexes. By drawing general conclusions, this review offers an insight into the coordination and catalytic behavior of phosphine ligands containing ionic functionalities and their corresponding metal complexes." @default.
- W2168613871 created "2016-06-24" @default.
- W2168613871 creator A5001582746 @default.
- W2168613871 creator A5050300271 @default.
- W2168613871 creator A5089521767 @default.
- W2168613871 date "2010-12-15" @default.
- W2168613871 modified "2023-10-16" @default.
- W2168613871 title "Steric, Electronic, and Secondary Effects on the Coordination Chemistry of Ionic Phosphine Ligands and the Catalytic Behavior of Their Metal Complexes" @default.
- W2168613871 cites W103291880 @default.
- W2168613871 cites W1894717839 @default.
- W2168613871 cites W1963825575 @default.
- W2168613871 cites W1965189852 @default.
- W2168613871 cites W1968066170 @default.
- W2168613871 cites W1969155048 @default.
- W2168613871 cites W1969687036 @default.
- W2168613871 cites W1971887129 @default.
- W2168613871 cites W1972907075 @default.
- W2168613871 cites W1972911699 @default.
- W2168613871 cites W1977156809 @default.
- W2168613871 cites W1979485902 @default.
- W2168613871 cites W1980377213 @default.
- W2168613871 cites W1981499719 @default.
- W2168613871 cites W1984898966 @default.
- W2168613871 cites W1986938821 @default.
- W2168613871 cites W1988163108 @default.
- W2168613871 cites W1992639294 @default.
- W2168613871 cites W1993312808 @default.
- W2168613871 cites W1993605313 @default.
- W2168613871 cites W1997619436 @default.
- W2168613871 cites W2000422092 @default.
- W2168613871 cites W2001003052 @default.
- W2168613871 cites W2002447659 @default.
- W2168613871 cites W2003099894 @default.
- W2168613871 cites W2004885353 @default.
- W2168613871 cites W2005359565 @default.
- W2168613871 cites W2007238709 @default.
- W2168613871 cites W2008705365 @default.
- W2168613871 cites W2009688806 @default.
- W2168613871 cites W2010162483 @default.
- W2168613871 cites W2012214028 @default.
- W2168613871 cites W2012884913 @default.
- W2168613871 cites W2016208813 @default.
- W2168613871 cites W2019699481 @default.
- W2168613871 cites W2019831901 @default.
- W2168613871 cites W2020989332 @default.
- W2168613871 cites W2021669297 @default.
- W2168613871 cites W2027689170 @default.
- W2168613871 cites W2027848858 @default.
- W2168613871 cites W2033367506 @default.
- W2168613871 cites W2033872102 @default.
- W2168613871 cites W2036609730 @default.
- W2168613871 cites W2037374692 @default.
- W2168613871 cites W2037665007 @default.
- W2168613871 cites W2039515729 @default.
- W2168613871 cites W2039823515 @default.
- W2168613871 cites W2041185596 @default.
- W2168613871 cites W2041386507 @default.
- W2168613871 cites W2045200945 @default.
- W2168613871 cites W2045985082 @default.
- W2168613871 cites W2047979484 @default.
- W2168613871 cites W2049464451 @default.
- W2168613871 cites W2049951486 @default.
- W2168613871 cites W2050145816 @default.
- W2168613871 cites W2051413294 @default.
- W2168613871 cites W2053259713 @default.
- W2168613871 cites W2055816746 @default.
- W2168613871 cites W2055874734 @default.
- W2168613871 cites W2056857186 @default.
- W2168613871 cites W2057862038 @default.
- W2168613871 cites W2057983092 @default.
- W2168613871 cites W2059889006 @default.
- W2168613871 cites W2061431152 @default.
- W2168613871 cites W2061610215 @default.
- W2168613871 cites W2063758436 @default.
- W2168613871 cites W2069134249 @default.
- W2168613871 cites W2073227110 @default.
- W2168613871 cites W2073754233 @default.
- W2168613871 cites W2075622879 @default.
- W2168613871 cites W2075684503 @default.
- W2168613871 cites W2076063450 @default.
- W2168613871 cites W2079231720 @default.
- W2168613871 cites W2083930498 @default.
- W2168613871 cites W2083944732 @default.
- W2168613871 cites W2084082487 @default.
- W2168613871 cites W2086214976 @default.
- W2168613871 cites W2086644087 @default.
- W2168613871 cites W2087947900 @default.
- W2168613871 cites W2088072796 @default.
- W2168613871 cites W2090079540 @default.
- W2168613871 cites W2090355810 @default.
- W2168613871 cites W2090423717 @default.
- W2168613871 cites W2090901280 @default.
- W2168613871 cites W2091702998 @default.
- W2168613871 cites W2092573876 @default.
- W2168613871 cites W2094571439 @default.
- W2168613871 cites W2110073376 @default.
- W2168613871 cites W2110620087 @default.
- W2168613871 cites W2119487440 @default.