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• W2168682842 abstract "Reaction of [Ir(COD)(py–ItBu)]+ (py–ItBu = 3-tert-butyl-1-picolylimidazol-2-ylidene) with acetonitrile results in reversible intramolecular C–H bond activation of the NHC ligand and formation of [Ir(η2:η1-C8H13)(py–ItBu′)(NCMe)]+. Coordinated COD acts as an internal hydride acceptor and acetonitrile coordination offsets the otherwise unfavourable thermodynamics of the process." @default.
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• W2168682842 date "2014-01-01" @default.
• W2168682842 modified "2023-09-25" @default.
• W2168682842 title "Solvent promoted reversible cyclometalation in a tethered NHC iridium complex" @default.
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• W2168682842 doi "https://doi.org/10.1039/c3cc48015a" @default.
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