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- W2168793089 abstract "Olefins can be converted to their respective epoxides in a one-pot procedure by dissolving the olefin in anhydrous DMSO, adding NBS to the reaction mixture to generate a β-bromoalkoxydimethylsulfonium ylide, and then adding DBU to the reaction mixture. A large variety of alkenes were successfully epoxidized with yields largely dependent on the structure of the alkene. Most importantly, the facial selectivity of this one-pot process is the opposite of that observed when using traditional epoxidizing reagents. Electron-poor alkenes are not epoxidized under these conditions." @default.
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- W2168793089 date "2010-12-01" @default.
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- W2168793089 title "Epoxidation of olefins by β-bromoalkoxydimethylsulfonium ylides" @default.
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- W2168793089 doi "https://doi.org/10.1016/j.tetlet.2010.10.068" @default.
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