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- W2168849697 abstract "N-(α-Methylallyl)pyridiniums rearrange to the N-(γ-methylallyl) analogues in a process analogous to ion return. In the tricyclic series the process (9)→(4) occurs spontaneously. In the monocyclic series (1) can be isolated and thermally rearranged into (2); this rearrangement is intramolecular. N-(α-Phenylethyl)pyridiniums solvolyse in HOAc–NEt3 with predominant inversion of configuration (90%). In the 2,4,6-triphenyl series this occurs spontaneously. The isolated 1-(α-phenylethyl)-2-isopropyl-4,6-diphenylpyridinium solvolyses in chlorobenzene with first-order kinetics and with racemisation." @default.
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- W2168849697 date "1983-01-01" @default.
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- W2168849697 title "Kinetics and mechanisms of nucleophilic displacements with heterocycles as leaving groups. Part 12. Regio- and stereo-chemistry of nucleophilic displacement and solvolysis reactions of N-(α-methylallyl)-and N-(α-phenylethyl)-pyridiniums" @default.
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- W2168849697 doi "https://doi.org/10.1039/p29830001449" @default.
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