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- W2168882768 abstract "Using a newly constructed Fourier transform emission apparatus, we have measured the threefold substituted HCN isotopomer, D13C15N, at 1370 K in the range from 450 to 700 cm−1. We could assign hot bands with upper states up to Kvl2= 1212. The assignments have been verified for states up tov2= 5 by fitting with earlier room temperature absorption measurements of overtone and hot bands. The intensities are shown to be in qualitative agreement with the expected intensity pattern for such emission spectra. All the measurements for D13C15N have been combined in a single least-squares fit that includes approximately 2700 rovibrational lines which have a root-mean-square deviation on the order of 0.000 4 cm−1. The spectroscopic constants for the bending statesv2= 1, … ,12 are reported, as well as for some combination states involving the other vibrational modes. We also give the spectroscopic constants of various states of DCN, D13C14N, and D12C15N which where obtained from room temperature absorption measurements." @default.
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- W2168882768 date "1999-06-01" @default.
- W2168882768 modified "2023-10-18" @default.
- W2168882768 title "Climbing the Bending Vibrational Ladder in D13C15N by Hot Gas Emission Spectroscopy" @default.
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- W2168882768 doi "https://doi.org/10.1006/jmsp.1999.7794" @default.
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