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- W2168892731 abstract "Preparation and properties of several highly stable nitroso complexes of rhenium viz. ReCl3(NO), Re(OH)3(NO)3 M2ReCl5(NO) where M is Cs, K and NH4 are described. These are analogous to the corresponding ruthenium complexes. The oxidation number of the ‘ReNO’ unit as a whole, is +3 but that of the rhenium atom cannot be determined. The nitric oxide stretching band lies within the range of 1710–1920 cm−1. The cesium and potassium salts are weakly paramagnetic at room temperature.Herstellung und Eigenschaften einiger sehr stabiler Nitrosylkomplexe des Rheniums werden beschrieben: ReCl3(NO), Re(OH)3(NO), M2ReCl5(NO), wobei M = K, Cs, NH4. Sie sind den entsprechenden Rutheniumkomplexen analog. Die Oxydationsstufe der Gruppe ReNO ist +3, wobei die des Re-Atoms allein aber nicht ermittelt werden konnte. Die νNO-Valenzschwingung liegt im Bereich 1710–1920 cm−;1. Das obige Kalium- und Casium-salz sind bei Raumtemperatur schwach paramagnetisch." @default.
- W2168892731 created "2016-06-24" @default.
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- W2168892731 date "1972-01-01" @default.
- W2168892731 modified "2023-09-23" @default.
- W2168892731 title "Chloronitrosyl complexes of rhenium" @default.
- W2168892731 cites W1972021288 @default.
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- W2168892731 doi "https://doi.org/10.1002/zaac.19723870214" @default.
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