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- W2168925665 abstract "Anion femtosecond photoelectron spectroscopy was used to follow the dynamics of the I 2 − (Ar) 6 and I 2 − (Ar) 20 clusters subsequent to photodissociation of the I 2 − chromophore. The experiments showed that photodissociation of the I 2 − moiety in I 2 − (Ar) 6 is complete by approximately 200 femtoseconds, just as in bare I 2 − , but also that attractive interactions between the departing anion fragment and the solvent atoms persisted for 1200 femtoseconds. Photodissociation of I 2 − (Ar) 20 results in caging of the I 2 − followed by recombination and vibrational relaxation on the excited à 2 Π g ,3/2 and the ground X̃ 2 Σ u + states; these processes are complete in 35 and 200 picoseconds, respectively." @default.
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- W2168925665 date "1997-06-13" @default.
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- W2168925665 title "Photodissociation of I <sub>2</sub> <sup>−</sup> (Ar) <sub> <i>n</i> </sub> Clusters Studied with Anion Femtosecond Photoelectron Spectroscopy" @default.
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- W2168925665 doi "https://doi.org/10.1126/science.276.5319.1675" @default.
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