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• W2168956898 abstract "Abstract A new type of Zintl phase is presented that contains endohedrally filled clusters and that allows for the formation of intermetalloid clusters in solution by a one‐step synthesis. The intermetallic compound K 5− x Co 1− x Sn 9 was obtained by the reaction of a preformed CoSn alloy with potassium and tin at high temperatures. The diamagnetic saltlike ternary phase contains discrete [Co@Sn 9 ] 5− clusters that are separated by K + ions. The intermetallic compound K 5− x Co 1− x Sn 9 readily and incongruently dissolves in ethylenediamine and in the presence of 4,7,13,16,21,24‐hexaoxa‐1,10‐diazabicyclo[8.8.8]hexacosane (2.2.2‐crypt), thereby leading to the formation of crystalline [K([2.2.2]crypt)] 5 [Co 2 Sn 17 ]. The novel polyanion [Co 2 Sn 17 ] 5− contains two Co‐filled Sn 9 clusters that share one vertex. Both compounds were characterized by single‐crystal X‐ray structure analysis. The diamagnetism of K 5− x Co 1− x Sn 9 and the paramagnetism of [K([2.2.2]crypt)] 5 [Co 2 Sn 17 ] have been confirmed by superconducting quantum interference device (SQUID) and EPR measurements, respectively. Quantum chemical calculations reveal an endohedral Co 1− atom in an [Sn 9 ] 4− nido cluster for [Co@Sn 9 ] 5− and confirm the stability of the paramagnetic [Co 2 Sn 17 ] 5− unit." @default.
• W2168956898 created "2016-06-24" @default.
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• W2168956898 date "2012-08-09" @default.
• W2168956898 modified "2023-10-18" @default.
• W2168956898 title "The Neat Ternary Solid K_5−<i>x</i>Co_1−<i>x</i>Sn₉with Endohedral [Co@Sn₉]⁵⁻Cluster Units: A Precursor for Soluble Intermetalloid [Co₂@Sn₁₇]⁵⁻Clusters" @default.
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• W2168956898 doi "https://doi.org/10.1002/chem.201201786" @default.
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