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• W2169010393 endingPage "3763" @default.
• W2169010393 startingPage "3747" @default.
• W2169010393 abstract "Abstract The interaction of uranyl nitrate with the series of diamides Et 2 N(C=O)(CH 2 ) n (C=O)NEt 2 (0 ≤ n ≤ 6) was investigated to evaluate systematically the effect of the (CH 2 ) n spacer on the solid‐state structures of the corresponding uranyl complexes. Under aerobic conditions, [UO 2 (NO 3 ) 2 · 6H 2 O] reacted with an excess amount of these diamides ( L ) in organic solvents to yield [UO 2 (κ 2 ‐NO 3 ) 2 ( L )] { 1 [ n = 0, tetraethyloxalamide (TEOA)], 2 [ n = 1, tetraethylmalonamide (TEMA)], 3 [ n = 2, tetraethylsuccinamide (TESA)], 5 [ n = 3, tetraethylglycolamide (TEGA)], 6 [ n = 4, tetraethyladipicamide (TEAA)], 7 [ n = 5, tetraethylpimelicamide (TEPA)], and 8 [ n = 6, tetraethylsubericamide (TESUA)]}, which were isolated and characterized by 1 H NMR, ESI‐MS, IR, and Raman spectroscopy. Under anhydrous and anaerobic conditions, [UO 2 (OTf) 2 ] (OTf = trifluoromethanesulfonate) was treated with an excess amount of L to give [UO 2 ( L ) 2 ][OTf] 2 , which was isolated for n = 1 ( 9 ) and n = 2 ( 10 ). The crystal structures of 2 , 5 , 6 , 7 , 8 , and of the peroxido‐bridged complex [{UO 2 (κ 2 ‐NO 3 )( L )} 2 (μ,η 2 ,η 2 ‐O 2 )] ( 4 ; n = 2) are presented. In all cases, the uranium ion is eight‐coordinated with a classical hexagonal‐bipyramidal configuration. The number of CH 2 groups in the diamide central chain has considerable influence on the dimensionality of the complexes. They are monometallic ( n = 1, 2), dimeric ( n = 3, 4), or polymeric ( n = 5, 6) with either a helical or zigzag structure, depending on the coordination mode of the bidentate diamide, which can be bridging or not, and the position cis or trans of the nitrate ions. DFT calculations in the gas phase show that the mono‐ and κ 2 ‐bidentate coordination modes of the diamide (1 ≤ n ≤ 5) onto [UO 2 (κ 2 ‐NO 3 ) 2 ] are energetically similar. By using the continuum solvation model, the binding affinity of the κ 2 ‐bidentate diamide gradually decreases with the increase in n , but the most stable bidentate uranyl complex is obtained for n = 1 (TEMA). The structural differences in the series of [UO 2 (κ 2 ‐NO 3 ) 2 {Et 2 N(C=O)(CH 2 ) n (C=O)NEt 2 }] complexes are directly related to the length of the (CH 2 ) n spacer." @default.
• W2169010393 created "2016-06-24" @default.
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• W2169010393 date "2012-07-06" @default.
• W2169010393 modified "2023-10-18" @default.
• W2169010393 title "Structural Versatility of Uranyl(VI) Nitrate Complexes That Involve the Diamide Ligand Et ₂ N(C=O)(CH ₂ ) <i> _n </i> (C=O)NEt ₂ (0 ≤ <i>n</i> ≤ 6)" @default.
• W2169010393 cites W1496336408 @default.
• W2169010393 cites W1539796472 @default.
• W2169010393 cites W1749872958 @default.
• W2169010393 cites W1968004729 @default.
• W2169010393 cites W1970673604 @default.
• W2169010393 cites W1971032586 @default.
• W2169010393 cites W1973977337 @default.
• W2169010393 cites W1976226515 @default.
• W2169010393 cites W1977196720 @default.
• W2169010393 cites W1977268375 @default.
• W2169010393 cites W1977495874 @default.
• W2169010393 cites W1979275278 @default.
• W2169010393 cites W1981477795 @default.
• W2169010393 cites W1985279082 @default.
• W2169010393 cites W1990838076 @default.
• W2169010393 cites W1992657376 @default.
• W2169010393 cites W1992710643 @default.
• W2169010393 cites W1996046920 @default.
• W2169010393 cites W1997914185 @default.
• W2169010393 cites W2000294877 @default.
• W2169010393 cites W2000659648 @default.
• W2169010393 cites W2001368737 @default.
• W2169010393 cites W2003486680 @default.
• W2169010393 cites W2005731716 @default.
• W2169010393 cites W2005862278 @default.
• W2169010393 cites W2006850167 @default.
• W2169010393 cites W2011059951 @default.
• W2169010393 cites W2013554384 @default.
• W2169010393 cites W2015578334 @default.
• W2169010393 cites W2015637534 @default.
• W2169010393 cites W2016196963 @default.
• W2169010393 cites W2017384220 @default.
• W2169010393 cites W2018985418 @default.
• W2169010393 cites W2019578380 @default.
• W2169010393 cites W2020063757 @default.
• W2169010393 cites W2021138758 @default.
• W2169010393 cites W2021891449 @default.
• W2169010393 cites W2022973164 @default.
• W2169010393 cites W2024430090 @default.
• W2169010393 cites W2024445225 @default.
• W2169010393 cites W2032447994 @default.
• W2169010393 cites W2032842297 @default.
• W2169010393 cites W2033882808 @default.
• W2169010393 cites W2034546089 @default.
• W2169010393 cites W2036689844 @default.
• W2169010393 cites W2037498688 @default.
• W2169010393 cites W2041067584 @default.
• W2169010393 cites W2048129158 @default.
• W2169010393 cites W2048492373 @default.
• W2169010393 cites W2054359802 @default.
• W2169010393 cites W2056697051 @default.
• W2169010393 cites W2059020082 @default.
• W2169010393 cites W2059191894 @default.
• W2169010393 cites W2060623574 @default.
• W2169010393 cites W2065655424 @default.
• W2169010393 cites W2065938228 @default.
• W2169010393 cites W2068501999 @default.
• W2169010393 cites W2069773728 @default.
• W2169010393 cites W2074070002 @default.
• W2169010393 cites W2077994026 @default.
• W2169010393 cites W2085055416 @default.
• W2169010393 cites W2085276927 @default.
• W2169010393 cites W2086288648 @default.
• W2169010393 cites W2086945873 @default.
• W2169010393 cites W2088812734 @default.
• W2169010393 cites W2089795139 @default.
• W2169010393 cites W2091129249 @default.
• W2169010393 cites W2094063937 @default.
• W2169010393 cites W2095309897 @default.
• W2169010393 cites W2105540031 @default.
• W2169010393 cites W2115580436 @default.
• W2169010393 cites W2129613952 @default.
• W2169010393 cites W2131220856 @default.
• W2169010393 cites W2131350133 @default.
• W2169010393 cites W2140139976 @default.
• W2169010393 cites W2144309335 @default.
• W2169010393 cites W2152207101 @default.
• W2169010393 cites W2159794008 @default.
• W2169010393 cites W2267348230 @default.
• W2169010393 cites W2314895770 @default.
• W2169010393 cites W2319408892 @default.
• W2169010393 cites W2321886573 @default.
• W2169010393 cites W2413178763 @default.
• W2169010393 cites W2481114765 @default.
• W2169010393 cites W2500075095 @default.

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