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• W2169014241 endingPage "4177" @default.
• W2169014241 startingPage "4168" @default.
• W2169014241 abstract "Abstract A one‐pot sequential Cu I ‐catalyzed azide–alkyne cycloaddition (CuAAC) strategy is presented for the synthesis of constitutionally unsymmetrical cyclobis(paraquat‐ p ‐phenylene)‐based rotaxanes in good yields from simple starting materials. The methodology consists of performing multiple CuAAC reactions to stopper a pseudorotaxane in a stepwise manner, the order of which is controlled through silyl‐protection and Ag I ‐catalyzed deprotection of a terminal alkyne. The methodology is highlighted by the synthesis of an amphiphilic branched [4]rotaxane. The methodology increases the ability to access ever more complicated mechanically interlocked compounds to serve in devices as sophisticated and functional molecular machinery." @default.
• W2169014241 created "2016-06-24" @default.
• W2169014241 creator A5031439932 @default.
• W2169014241 creator A5032990625 @default.
• W2169014241 creator A5059309194 @default.
• W2169014241 creator A5089719740 @default.
• W2169014241 date "2008-04-29" @default.
• W2169014241 modified "2023-10-18" @default.
• W2169014241 title "A One-Pot Synthesis of Constitutionally Unsymmetrical Rotaxanes Using Sequential CuI-Catalyzed Azide–Alkyne Cycloadditions" @default.
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• W2169014241 doi "https://doi.org/10.1002/chem.200800067" @default.
• W2169014241 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18384025" @default.
• W2169014241 hasPublicationYear "2008" @default.
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