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- W2169064025 abstract "[2678-54-8] C6H12O2 (MW 116.18) InChI = 1S/C6H12O2/c1-4-7-6(3)8-5-2/h3-5H2,1-2H3 InChIKey = VTGIVYVOVVQLRL-UHFFFAOYSA-N (inverse electron demand Diels–Alder reactions; thermal and photochemical [2 + 2] cycloadditions; naphthoquinone and anthraquinone synthesis; Paterno–Büchi photocycloadditions) Physical Data: bp 68 °C/100 mmHg, 84–86 °C/200 mmHg. 1.4411. Solubility: sol THF, ether, benzene; decomposes in water, ethanol. Form Supplied in: liquid, not commercially available. Preparative Method: reaction of 2-bromo-1,1-diethoxyethane with potassium t-butoxide in t-butanol;1reaction of 2-methoxyethanol with sodium metal and vinylidene chloride in p-xylene.29 Handling, Storage, and Precautions: storage at 0 °C in an alkaline glass bottle dusted with potassium t-butoxide is recommended." @default.
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- W2169064025 date "2009-09-15" @default.
- W2169064025 modified "2023-09-24" @default.
- W2169064025 title "Ketene Diethyl Acetal" @default.
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- W2169064025 doi "https://doi.org/10.1002/047084289x.rk003.pub2" @default.
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