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- W2169198601 abstract "Mossbauer spectra of 57Fe probe atoms in the spinel Co2.94Fe0.06S4 indicate the existence of a magnetic transition at Ttr ~ 95 K in the parent phase Co3S4. The spectrum observed below Ttr consists of a six-line magnetic spectrum and a two-line quadrupole spectrum. Above Ttr the six-line spectrum collapses to a single line superposed on the two-line quadrupole spectrum. Consideration of the Mossbauer parameters and of the area ratio of the component spectra suggests that the atomic occupancy of the spinel lattice is [Co0.968Fe3+(HS)0.032][Co0.968Fe2+(LS)0.014]2S4, the Fe atoms having preference for the tetrahedrally coordinated cation sites." @default.
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- W2169198601 date "1976-12-01" @default.
- W2169198601 modified "2023-09-27" @default.
- W2169198601 title "MÖSSBAUER EFFECT IN THE SPINEL Co2.94 Fe0.06S4 BETWEEN 10 K AND ROOM TEMPERATURE" @default.
- W2169198601 doi "https://doi.org/10.1051/jphyscol:19766118" @default.
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