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• W2169228921 startingPage "12842" @default.
• W2169228921 abstract "Activated: The title reaction proceeds efficiently with 1 mol % of palladium and gives tetrahydroquinolines in excellent enantioselectivities (see scheme). The enantiodiscriminating concerted metalation–deprotonation step occurs via a rare seven-membered palladacycle. The cyclopropyl-substituted tetrahydroquinolines can be regioselectively and enantiospecifically reduced to chiral tetrahydrobenzoazepines. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
• W2169228921 created "2016-06-24" @default.
• W2169228921 creator A5018021290 @default.
• W2169228921 creator A5025436040 @default.
• W2169228921 date "2012-11-19" @default.
• W2169228921 modified "2023-10-18" @default.
• W2169228921 title "Palladium(0)-Catalyzed Enantioselective CH Arylation of Cyclopropanes: Efficient Access to Functionalized Tetrahydroquinolines" @default.
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• W2169228921 doi "https://doi.org/10.1002/anie.201207959" @default.
• W2169228921 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23161777" @default.
• W2169228921 hasPublicationYear "2012" @default.
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