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• W2169347804 abstract "Abstract An unprecedented way to extend the synthetic utility of the Diels–Alder reaction to include a vinylogous reactivity space is described. A commercially available chiral phosphoric acid catalyst effectively activates cyclic 2,4‐dienones towards a vinylogous [4+2] cycloaddition with 2‐vinylindoles, which leads to stereochemically dense tetrahydrocarbazoles. The reaction proceeds with a high level of remote stereocontrol and exclusive chemoselectivity for the more distant double bond of the dienone." @default.
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• W2169347804 date "2014-02-06" @default.
• W2169347804 modified "2023-10-18" @default.
• W2169347804 title "Asymmetric Vinylogous Diels-Alder Reactions Catalyzed by a Chiral Phosphoric Acid" @default.
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• W2169347804 doi "https://doi.org/10.1002/anie.201310487" @default.
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