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- W2169376465 abstract "Abstract A coordination polymer of the formula 1 ∞ [Pr(BSB) 3 (py) 2 ] constituted of bis(salicylato)borate anions ([BSB] – ) and Pr 3+ was synthesized as single crystals from the sodium salt under solvothermal conditions in pyridine. The formation of sodium chloride is a driving force valid for a reaction under solvothermal and ionothermal conditions using the ionic liquid (IL) 1‐ethyl‐3‐methylimidazolium‐bis(salicylato)borate [EMIM][BSB]. For the formation of isoconstitutional compounds the latter reaction also requires a certain amount of pyridine, which is beneficial for crystallization. In addition, a different precursor has to be employed: whilst the solvothermal reaction can be carried out with the anhydrous halide Ln Cl 3 , the IL‐based reaction is only successful with the complex [ Ln Cl 3 (py) 4 ] as precursor." @default.
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- W2169376465 date "2015-01-13" @default.
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- W2169376465 title "<sup>1</sup><sub>∞</sub>[Pr(BSB)<sub>3</sub>(py)<sub>2</sub>]: A Lanthanide Bis(salicylato)borate at the Junction between Solvothermal and Ionothermal Conditions" @default.
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- W2169376465 doi "https://doi.org/10.1002/zaac.201400498" @default.
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